The company employed four pan coaters in series. Each had an exhaust tube connected to a common duct leading to a wet dust collector as well as an air connection utilizing a common air supply. On the day of the incident, two of the four pan coaters required cleaning due to a layer of latex and chemical that adhered to the inside of the pan. The cleaning process presented a challenge since the pan geometry made it difficult to clean, and the well-cured coating adhering to the pan proved stubbornly resistant to scraping, chipping and other physical means of attack.
In frustration at the difficulty of removing the residual coating, an employee began to chisel at it forcefully with a large and heavy steel pry bar. The repeated blows from the pry bar caused a roughly 2 inch diameter area on the exterior of the pan to glow red from heat. Two employees then observed the red spot rapidly grow to approximately 6 to 8 inches in size. At this time, they chose to evacuate the room. Approximately 20 seconds later an explosion occurred.
There was no explosion isolation in place between the pan coaters to prevent deflagration propagation between the interconnected pieces of equipment. Such isolation is recommended by NFPA 654, Standard for the Prevention of Fire and Dust Explosions from the Manufacturing, Processing, and Handling of Combustible Particulate Solids. As a result the deflagration pressure wave and fire generated from the incident spread out of the pan coater mouth and through the exhaust ductwork to the other interconnected coaters. Due to overpressure, the exhaust system ductwork ruptured. Residual coating material in the other dirty pan coaters also ignited. Thankfully, no personnel were injured.
In an effort to characterize the events that led to the incident, several Differential Scanning Calorimetry (DSC) tests were performed using several ratios of coating to oxidizer material. The most energetic sample was then tested in various forms for drop weight impact (BAM Fallhammer) testing. It should be noted that samples 3 and 6 were wet material.
Though this process was not covered by OSHA Process Safety Management (PSM), several elements of PSM were utilized to reduce risk, improve methods, review management systems and ensure that personnel were aware of critical tasks.
Updated process safety information was used to reduce risks associated with this process:
Several alternative cleaning strategies were investigated and a non-impact method was selected.
Spray methodology was changed to reduce the accumulation of coating on the inside wall of the pan coaters by improving the angle of the spray and reducing the timing of the spray.
Employee involvement in the review of procedures was critical to understand current practices, evaluate potential alternatives and obtain employee support for the procedure changes that followed